Science●●●●●Difficulty 5 of 5

Where do hydrogen and helium really belong in the periodic table?

The periodic table on the classroom wall hides an argument: hydrogen fits no column well, and some chemists want helium moved next to beryllium.

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Hydrogen and helium do not fit cleanly anywhere, and that is why chemists still argue about them. Although the modern periodic table is standard, the placement of the period 1 elements, hydrogen and helium, remains an open issue under discussion, and some variation can be found. In practice hydrogen usually sits in group 1 and helium almost always in group 18, but each placement is a compromise.

By electron configuration alone, hydrogen would go in group 1 and helium in group 2. Hydrogen in group 1 is common, since like the group 1 metals it has one outer electron and typically loses it in reactions. But hydrogen also forms hydrides by gaining an electron, as halogens do, and the lightest halogens are gases like hydrogen. It matches neither group perfectly, and is difficult to place by its chemistry. Rarer layouts put it in group 17, in both groups 1 and 17, or floating outside all groups.

The case for each home of hydrogen

Group 1 (alkali metals)

  • One outer electron
  • Typically loses it in reactions

Group 17 (halogens)

  • Forms hydrides by gaining an electron
  • Lightest halogens are gases like hydrogen

Helium is almost always placed in group 18 with the noble gases, because it is unreactive and has a full outer shell. But it has two outer electrons while the other noble gases have eight, and it is an s-block element while they are p-block. Solid helium crystallises like beryllium and magnesium in group 2. IUPAC rejected a proposal to move helium to group 2 in 1988, but recent theory suggesting that helium could form a compound like beryllium's has led more chemists to advocate placing it there.

Quiz me

0/3

  1. 1.Why is hydrogen hard to place in the periodic table?
  2. 2.Why do some chemists argue helium belongs in group 2?
  3. 3.What is the standard placement, and what did IUPAC do about moving helium?

Recap

Hydrogen resembles both alkali metals and halogens, and helium resembles noble gases in behaviour but beryllium in electron count.

💡 A trick to remember it · Hydrogen wears two hats, helium wears a noble gas's coat over a group 2 body.

Surprising fact · Floating hydrogen outside all groups has been criticised for implying it is above the periodic law.

Sources (3)

No source, no claim. Every fact in this lesson (16 claims) cites at least one of these.

  1. [1]Periodic table · Wikipedia
  2. [2]Helium · Wikipedia
  3. [3]Noble gas · Wikipedia
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